CHEMIStry*?

what is [H3O] in 0.70M HCN?

answer is 1.9×10^-5, how do you figure out?

2 Responses to “CHEMIStry*?”

  • Dennis M:

    You need Ka to solve it. My book (Zuhmdahl, 5th ed.) says it is 6.2 X 10^-10.

    HCN = H+ + CN-

    Let "X" equal [H+] and [CN-].

    Ka = [H+][CN-] / [HCN] = 6.2 X 10^-10

    X^2 / 0.70 = 6.2 X10^-10

    X^2 = 4.34 X 10^-10

    X = ( 4.34 X 10^-10)^0.5

    X = 2.08 X 10^-5

    So [H+] = [H3O+] = 2.08 X 10^-5 M

    The slight difference in answers is probably because your textbook has a different Ka value for HCN.

  • RONALD E B:

    Ka for HCN = 6.0×10^-10
    Ka = [H+][CN-]/[HCN]
    after X moles/l have dissociated the concentrations are-
    [H+] = X
    [CN-] = X
    [HCN] = 0.70 – X
    Since Ka is very small, we know X << 0.70, so we can assume [HCN] = 0.70 (to 2 significant figures)
    6.0×10^-10 = X^2 / 0.70
    4.2×10^-10 = X^2
    X = 2.0×10^-5
    Perhaps your textbook gives a different value of Ka.
    1.9×10^-5 would be the correct answer if the value of Ka was 5.2×10^-10
    1.9×10^-5 would be the correct answer if Ka = 6.0×10^-10 and the concentration of HCN was 0.60 M (not 0.70 M)

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